Who Really Discovered Oxygen? The Story History Forgot

18th-century oil portrait of Carl Wilhelm Scheele (1742–1786), Swedish chemist, seated in a red coat, holding a paper showing chemical apparatus, c. 1775.

The Forgotten Genius Who Changed Chemistry Forever

What if the man who first isolated the oxygen you're breathing right now never received a single line of credit for it?

Welcome to FreeAstroScience.com — where we explain complex scientific principles in plain, honest language. We're Gerd Dani, writing to you as always from our community that refuses to let good science go unnoticed. Today we tell the story of Carl Wilhelm Scheele: an 18th-century pharmacist who discovered more chemical elements and compounds than almost anyone in history — and was quietly erased from the textbooks anyway.

It's a story about genius, bad timing, possible academic theft, and a truly tragic ending. Read it to the end. We promise it's worth every minute.

Who Was Carl Wilhelm Scheele?

Born on 9 December 1742 in Stralsund — a small Baltic coastal town then under Swedish rule, now part of Germany — Scheele grew up as one of eleven children of an unsuccessful brewer. Not exactly the biography you'd expect for one of history's most productive chemists.

At just 14 years old, he became an apprentice apothecary in Gothenburg. That pharmacy bench was his real university. Over the next three decades, he moved through Malmö, Stockholm, and Uppsala before settling permanently in the quiet provincial town of Köping. He stayed there for the rest of his short life — mixing medicines by day, making world-changing discoveries in every spare hour.

No grand university laboratory. No wealthy patron. No prestigious title. Just a stove, a few glass flasks, and a curiosity that simply could not be switched off.

📌 Carl Wilhelm Scheele — Key Facts at a Glance
  • Born: 9 December 1742, Stralsund, Pomerania
  • Died: 21 May 1786, Köping, Sweden — aged 43
  • Profession: Pharmaceutical chemist and apothecary
  • Nationality: German-Swedish
  • Academy member: Royal Swedish Academy of Sciences, from 1775
  • Main publication: Chemical Observations and Experiments on Air and Fire, Uppsala & Leipzig, 1777
  • Estimated discoveries: 7 new elements, 4 gases, 6 inorganic acids, 8 organic acids, glycerin, and more

In 1775, the Royal Swedish Academy of Sciences elected him a member — a rare honour for a self-taught pharmacist. He attended only one meeting in his life. He was always too busy doing the actual science.

How Did He Discover Oxygen?

He Named It Feuerluft — "Fire-Air"

Between 1770 and 1774, while working in Uppsala alongside the chemistry professor Torbern Bergman, Scheele began heating a series of compounds: mercuric oxide, potassium nitrate, silver carbonate, manganese dioxide. Each time, the same result. A colourless, odourless gas appeared — and candles burned inside it with spectacular intensity.

He named it Feuerluft — "fire-air" in German. We know it today as oxygen. He described its properties carefully in letters and experimental notes. The discovery was real, methodical, and reproduced across multiple reactions. By any scientific standard, Scheele had found oxygen roughly a year before anyone else.

But he didn't publish until 1777. And that delay cost him everything.

⚗️ Reaction 1 — Scheele Isolates Oxygen by Heating Mercury(II) Oxide
2 HgO — Δ → 2 Hg + O2
Mercury(II) oxide (heated) → liquid mercury + oxygen gas
⚗️ Reaction 2 — Oxygen from Saltpeter (Potassium Nitrate)
2 KNO3 — Δ → 2 KNO2 + O2
Potassium nitrate (heated) → potassium nitrite + oxygen gas

He didn't stumble onto oxygen once and stop. He reproduced it from multiple different starting materials. That's not luck. That's rigorous chemistry.

Who Really Deserves the Credit for Discovering Oxygen?

Three men are tied to this discovery. History has not been equally kind to all of them.

Table 1. The three scientists connected to the discovery of oxygen — a timeline of discovery and publication.
Scientist Discovery (est.) Published Key Contribution
Carl Wilhelm Scheele c. 1772–1773 1777 First to isolate and describe "fire-air" (oxygen); published too late to claim credit
Joseph Priestley 1 August 1774 1775 Independent discovery; published first; called it "dephlogisticated air"
Antoine Lavoisier 1775 1777–1778 Correctly identified oxygen as a chemical element; debunked phlogiston theory; coined the name "oxygen"

Here's the part that still stings, 240 years later. Scheele wrote to Lavoisier — he sent the French chemist a detailed letter describing "fire-air" before Lavoisier had published anything on the subject. Lavoisier never acknowledged receiving that letter. Some historians have suggested that Lavoisier's wife — who managed his scientific correspondence — may have hidden the letter so her husband could claim the discovery as his own.

"Lavoisier characteristically did not acknowledge this. It has even been suggested that Lavoisier's wife hid the letter from her husband to allow him to claim credit for the discovery of oxygen."
American Journal of Physiology-Lung Cellular and Molecular Physiology, 2014

Scheele, for his part, still believed in the phlogiston theory — the old alchemical idea that a fire-element called phlogiston was released during combustion. So did Priestley. It was Lavoisier alone who discarded phlogiston entirely and explained oxygen's true role. He named it from the Greek oxys (acid) + genes (producer): oxygen. The name stuck. And so did his reputation — at Scheele's expense.

Science, like life, isn't always fair. But the facts don't bend to fame.

What Else Did Carl Wilhelm Scheele Discover?

Oxygen was just one chapter. In a career of barely 20 active years — working from a provincial pharmacy — Scheele arguably discovered seven new chemical elements and an extraordinary range of compounds. The full list is almost hard to believe.

Table 2. Confirmed discoveries attributed to Carl Wilhelm Scheele, 1770–1786.
Discovery Year Type Modern Name / Notes
Oxygen ("fire-air") c. 1772–73 Element — Gas O₂; first isolated; published last
Chlorine 1774 Element — Gas Cl₂; called "dephlogisticated muriatic acid"; named by Davy in 1810
Manganese 1774 Element Mn; identified from pyrolusite (black magnesia)
Barium 1772 Element Ba; announced as "baryta" (barium oxide)
Molybdenum 1778 Element Mo; extracted from molybdenite mineral
Tungsten 1781 Element W; the mineral scheelite (CaWO₄) still bears his name
Nitrogen (jointly) 1772 Element — Gas N₂; shared credit with Rutherford and Cavendish
Tartaric acid 1770 Organic acid C₄H₆O₆; found in wine sediment
Lactic acid 1780 Organic acid C₃H₆O₃; isolated from sour milk
Citric acid 1784 Organic acid C₆H₈O₇; isolated from lemon juice
Oxalic acid 1776 Organic acid (COOH)₂; present in many plants
Prussic acid (HCN) 1782 Inorganic acid Hydrogen cyanide; one of the most potent poisons known
Glycerol 1779 Organic compound C₃H₈O₃; still widely used in cosmetics and pharmaceuticals
Hydrofluoric acid 1771 Inorganic acid HF; highly corrosive; etches glass
Hydrogen sulfide 1777 Inorganic compound H₂S; the "rotten egg" gas
Scheele's Green 1775 Pigment Copper arsenite (CuHAsO₃); hugely popular in 19th-century wallpaper — later found toxic
Silver salt photodecomposition c. 1777 Principle Silver salts decompose under light — the founding principle of photography

That list covers 4 gases, 6 inorganic acids, 8 organic acids, isolated glycerin, and the groundwork for photography. He did all of this before any major institution gave him serious resources. If that doesn't make you stop and think, we don't know what will.

The Chemistry Behind the Breakthroughs

How Scheele Made Chlorine in 1774

Scheele's chlorine discovery came from reacting what he called "muriatic acid" (hydrochloric acid) with black magnesia (manganese dioxide). A sharp-smelling, yellowish-green gas appeared. He noted it bleached fabric, dissolved metals, and produced common salt when combined with soda. Despite all that evidence, his commitment to phlogiston theory meant he called it "dephlogisticated muriatic acid" rather than naming it a new element. Sir Humphry Davy finally confirmed it as an element in 1810.

⚗️ Reaction 3 — Scheele's Discovery of Chlorine (1774)
MnO2 + 4 HCl — Δ → MnCl2 + Cl2 + 2 H2O
Manganese dioxide + hydrochloric acid → manganese(II) chloride + chlorine gas + water

Prussic Acid — The Compound That Killed Him

In 1782, Scheele isolated prussic acid from Prussian blue pigment. He described its smell and, as was his habit, its taste. He had no idea what he was dealing with. We now call it hydrogen cyanide (HCN) — one of the fastest-acting, most potent poisons ever identified.

☠️ Prussic Acid — Hydrogen Cyanide (HCN)
H — C ≡ N (Hydrogen Cyanide — lethal at trace concentrations)
Lethal inhalation threshold: ~100–300 ppm. Oral lethal dose: approximately 1–3 mg per kg of body weight. Scheele tasted it without knowing any of this.

Why Did He Taste His Chemicals?

It sounds almost absurd by today's standards. But in the 18th century, sensory description was part of the scientific method. Chemists and naturalists were expected to note the colour, smell, texture, and taste of new substances. It was data. It was protocol.

Scheele followed this practice throughout his career. He inhaled chlorine, tasted prussic acid, and handled arsenic, mercury, and lead compounds with his bare hands — routinely, over decades. The concept of cumulative chemical toxicity barely existed in his time.

He wasn't reckless. He was a man of his era, doing exactly what the science of his era required. That's what makes his story so genuinely tragic. His most dangerous experiments were also, by the standards of 1774, perfectly normal ones.

How Did Carl Wilhelm Scheele Die?

By autumn 1785, Scheele was visibly deteriorating. He showed signs of kidney disease and a severe skin condition — both almost certainly the result of years of exposure to arsenic, mercury, lead, hydrofluoric acid, and other toxic compounds he had worked with unprotected.

He knew the end was coming. On 19 May 1786 — two days before his death — he married Sara Margaretha Pohl, the widow of his predecessor at the Köping pharmacy. The marriage had one practical purpose: so she could legally inherit the pharmacy and all his possessions. Even in dying, Scheele thought of someone else first.

He died on 21 May 1786, in Köping, Sweden. He was 43 years old.

"Cumulative exposure to arsenic, mercury, lead, and their compounds and, perhaps, hydrofluoric acid… took their toll on Scheele. He died at the early age of 43."
American Journal of Physiology, 2014

The document we studied for this article describes him being found dead one morning with an astonished expression — after conducting experiments with prussic acid. Whether that detail is precise or embellished in the retelling, the core truth doesn't change: the man who discovered hydrogen cyanide was almost certainly killed by it, and by the accumulated toll of his life's work.

The discoverer of oxygen died not knowing whether his own country would remember him. It's a sentence that should sit with you for a while.

What Is Scheele's Legacy Today?

Despite the injustice of the historical record, Scheele's name hasn't completely disappeared. You'll find traces of him in surprising places:

  • Scheelite (CaWO₄) — the calcium tungstate mineral named in his honour. It's used today in extracting tungsten for electronics, lighting filaments, and hard metal tools.
  • Scheele's Green (CuHAsO₃) — his copper arsenite pigment became the most popular green colour of the 19th century. It coloured wallpapers, fabrics, artificial flowers, and children's toys across Europe — until its arsenic content was finally linked to widespread illness decades later.
  • Chemical Observations and Experiments on Air and Fire (1777) — his landmark publication, still referenced in the history of chemistry.
  • Photography — his observation that silver salts decompose under light was the foundational principle on which the entire science of photography was later built.
  • A statue in Köping — the quiet Swedish town where he lived and died now honours him in bronze.
  • The Royal Swedish Academy of Sciences — recognised him as a member in 1775, while he was still alive. One of the few official recognitions he received.

We at FreeAstroScience believe his story matters far beyond the history of chemistry. It's a reminder that real discovery doesn't always come with a standing ovation. Sometimes it comes with silence. Sometimes it comes while you're standing alone in a small pharmacy on a cold Swedish morning.

We keep this site alive because — as we always say — the sleep of reason breeds monsters. Scheele never let his mind sleep. Not even when the academic world refused to wake up and notice him.

One Last Thought

Carl Wilhelm Scheele was a pharmacist in a small town. He had no famous university behind him, no powerful patrons, and no talent for self-promotion. What he had was an extraordinary mind and an inexhaustible appetite for discovery.

He isolated oxygen before anyone else — then got no credit for it. He wrote to Lavoisier about his findings — and the letter disappeared. He discovered chlorine, manganese, barium, molybdenum, tungsten, prussic acid, citric acid, glycerol, and the principle behind photography — and history largely forgot his name.

His story forces us to ask a hard question: how many other Scheeles are out there — brilliant, productive, honest scientists whose work was absorbed by more famous names, lost to bad timing, or simply never acknowledged?

We think you should hold onto that question. Good science deserves good memory. That's exactly why FreeAstroScience exists — to make sure these stories don't stay buried under the weight of more convenient narratives.

Come back to FreeAstroScience.com. There are more forgotten geniuses waiting to be rediscovered — and we'll be here to tell their stories clearly, honestly, and without putting you to sleep. Keep your mind active. Always.

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